The INT3 instruction is a one-byte-instruction defined for use by debuggers to temporarily replace an instruction in a running program in order to set a code breakpoint. The more general INT XXh instructions are encoded using two bytes. This makes them unsuitable for use in patching instructions (which can be one byte long); see SIGTRAP.
The opcode for INT3 is 0xCC, as opposed to the opcode for INT immediate8, which is 0xCD immediate8. Since the dedicated 0xCC opcode has some desired special properties for debugging, which are not shared by the normal two-byte opcode for an INT3, assemblers do not normally generate the generic 0xCD 0x03 opcode from mnemonics.